Introduction to Polymer Chemistry 3e

书籍目录

书籍简介

本书pdf是文字版，书签良好。

Introduction to Polymers

1.1 History of Polymers

1.2 Why Polymers?

1.3 Today’s Marketplace

1.4 Environmental Assessment

1.5 Managing Sustainability

1.6 Summary

Polymer Structure (Morphology)

2.1 Stereochemistry of Polymers

2.2 Molecular Interactions

2.3 Polymer Crystals

2.4 Amorphous Bulk State

2.5 Polymer Structure–Property Relationships

2.6 Crystalline and Amorphous Combinations

2.7 Cross-linking

2.8 Summary

Molecular Weight of Polymers

3.1 Introduction

3.2 Solubility

3.3 Average Molecular Weight Values

3.4 Fractionation of Polydisperse Systems

3.5 Chromatography

3.6 Colligative Molecular Weights

3.7 Light-Scattering Photometry

3.8 Other Techniques

3.9 Viscometry

3.10 Summary

Naturally Occurring Polymers

4.1 Polysaccharides

4.2 Cellulose

4.3 Cellulose-Regenerating Processes

4.4 Esters and Ethers of Cellulose

4.5 Starch

4.6 Other Polysaccharides

4.7 Proteins

4.8 Nucleic Acids

4.9 Naturally Occurring Polyisoprenes and Other Synthetic Elastomers

4.10 Lignin

4.11 Melanins

4.12 Polymer Structure

4.13 Genetic Engineering

4.14 DNA Profiling

4.15 Asphalt

4.16 Summary

Step-Reaction Polymerization (Polycondensation Reactions)

5.1 Comparison between Polymer Type and Kinetics of Polymerization

5.2 Introduction

5.3 Stepwise Kinetics

5.4 Polycondensation Mechanisms

5.5 Polyesters and Polycarbonates

5.6 Synthetic Polyamides

5.7 Polyimides

5.8 Polybenzimidazoles and Related Polymers

5.9 Polyurethanes and Polyureas

5.10 Polysulfides

5.11 Polyethers

5.12 Polysulfones

5.13 Poly(Ether Ether Ketone) and Polyketones

5.14 Phenolic and Amino Plastics

5.15 Synthetic Routes

5.16 Liquid Crystals

5.17 Microfibers

5.18 Summary

Ionic Chain-Reaction and Complex Coordination Polymerization (Addition Polymerization)

6.1 Cationic Polymerization

6.2 Anionic Polymerization

6.3 Stereoregularity and Stereogeometry

6.4 Polymerization with Complex Coordination Catalysts

6.5 Soluble Stereoregulating Catalysis

6.6 Polyethylenes

6.7 Polypropylene

6.8 Polymers from 1,4-Dienes

6.9 Polyisobutylene

6.10 Metathesis Reactions

6.11 Zwitterionic Polymerization

6.12 Isomerization Polymerization

6.13 Precipitation Polymerization

6.14 Summary

Free Radical Chain Polymerization (Addition Polymerization)

7.1 Initiators for Free Radical Chain Polymerization

7.2 Mechanism for Free Radical Chain Polymerization

7.3 Chain Transfer

7.4 Polymerization Techniques

7.5 Fluorine-Containing Polymers

7.6 Polystyrene

7.7 Poly(Vinyl Chloride)

7.8 Poly(Methyl Methacrylate)

7.9 Polyacrylonitrile

7.10 Solid-State Irradiation Polymerization

7.11 Plasma Polymerizations

7.12 Summary

Copolymerization

8.1 Kinetics of Copolymerization

8.2 The Q–e Scheme

8.3 Commercial Copolymers

8.4 Block Copolymers

8.5 Graft Copolymers

8.6 Elastomers

8.7 Blends

8.8 Polymer Mixtures: IPNS and Alloys

8.9 Dendrites

8.10 Ionomers

8.11 Fluoroelastomers

8.12 Nitrile Rubber

8.13 Acrylonitrile Butadiene Styrene Terpolymers

8.14 EPDM Rubber

8.15 Summary

Organometallic and Metalloid Polymers

9.1 Introduction

9.2 Inorganic Reaction Mechanisms

9.3 Condensation Organometallic Polymers

9.4 Coordination Polymers

9.5 Addition Polymers

9.6 Summary

Inorganic Polymers

10.1 Introduction

10.2 Portland Cement

10.3 Other Cements

10.4 Silicates

10.5 Silicon Dioxide (Amorphous)

10.6 Sol–Gel

10.7 Silicon Dioxide (Crystalline Forms): Quartz Forms

10.8 Silicon Dioxide in Electronic Chips

10.9 Asbestos

10.10 Fly Ash and Aluminosilicates

10.11 Polymeric Carbon: Diamond

10.12 Polymeric Carbon: Graphite

10.13 Internal Cyclization: Carbon Fibers and Related Materials

10.14 Carbon Nanotubes

10.15 Bitumens

10.16 Carbon Black

10.17 Polysulfur

10.18 Ceramics

10.19 High-Temperature Superconductors

10.20 Zeolites

10.21 Summary

Reactions of Polymers

11.1 Reactions with Polyolefins and Polyenes

11.2 Reactions of Aromatic and Aliphatic Pendant Groups

11.3 Degradation

11.4 Cross-Linking

11.5 Reactivities of End Groups

11.6 Supramolecules and Self-Assembly

11.7 Transfer and Retention of Oxygen

11.8 Nature’s Macromolecular Catalysts

11.9 Photosynthesis

11.10 Mechanisms of Energy Physical Absorption

11.11 Breakage of Polymeric Materials

11.12 Summary

Testing and Spectrometric Characterization of Polymers

12.1 Spectronic Characterization of Polymers

12.2 Surface Characterization

12.3 Amorphous Region Determinations

12.4 Thermal Analysis

12.5 Thermal Property Tests

12.6 Flammability

12.7 Electrical Properties: Theory

12.8 Electric Measurements

12.9 Weatherability

12.10 Optical Properties Tests

12.11 Chemical Resistance

12.12 Summary

Rheology and Physical Tests

13.1 Rheology

13.2 Typical Stress–Strain Behavior

13.3 Stress–Strain Relationships

13.4 Specific Physical Tests

13.5 Summary

Additives

14.1 Fillers

14.2 Reinforcements

14.3 Nanocomposites

14.4 Plasticizers

14.5 Antioxidants

14.6 Heat Stabilizers

14.7 Ultraviolet Stabilizers

14.8 Flame Retardants

14.9 Colorants

14.10 Curing Agents

14.11 Antistatic Agents: Antistats

14.12 Chemical Blowing Agents

14.13 Compatibilizers

14.14 Impact Modifiers

14.15 Processing Aids

14.16 Lubricants

14.17 Microorganism Inhibitors

14.18 Summary

Synthesis of Reactants and Intermediates for Polymers

15.1 Monomer Synthesis from Basic Feedstocks

15.2 Reactants for Step-Reaction Polymerization

15.3 Synthesis of Vinyl Monomers

15.4 Summary

Polymer Technology

16.1 Polymer Processing

16.2 Secondary Structures: Mesophases

16.3 Fibers

16.4 Elastomers

16.5 Films and Sheets

16.6 Polymeric Foams

16.7 Reinforced Plastics (Composites) and Laminates

16.8 Molding

16.9 Casting

16.10 Extrusion

16.11 Coatings

16.12 Adhesives

16.13 Conductive Polymeric Materials

16.14 Drug Design and Activity

16.15 Synthetic Biomedical Polymers

16.16 Dental Materials

16.17 Emerging Polymers

16.18 Green Materials

16.19 Summary