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出版商:The Royal Society of Chemistry
语言:英语
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书籍目录

书籍简介

本书pdf是文字版

Polymer Chemistry

1.1 Basic Concepts

1.2 The History of the Concept of the Macromolecule

1.3 Classification of Polymers

1.4 Structure and Properties of Polymers

Polymerisation Reactions

2.1 Chain Polymerisation

2.2 Arrangement of Monomer Units

2.3 Kinetics of Chain Polymerisation

2.4 Autoacceleration

2.5 Practical Methods of Chain Polymerisation

2.6 Other Chain Polymerisation Mechanisms

2.7 Step Polymerisation

2.8 Step polymerisation with Polyfunctional monomers

2.9 Copolymerisation

Polymer Structure

3.1 Polymer Stereochemistry

3.2 Polymer Crystallinity

3.3 Thermal and Mechanical Properties

Crosslinking

4.1 Introduction

4.2 Phenol–Formaldehyde Resins

4.3 Unsaturated Polyester Resins

4.4 Polyurethanes

4.5 Epoxy Resins

Polymer Solutions

5.1 Introduction

5.2 Dissolution of Polymers

5.3 Solubility Parameters

5.4 Simple Liquid Mixtures and Raoult's Law

5.5 Entropy of Mixing

5.6 Real Molecules in Dilute Solution

5.7 Shapes of Polymer Molecules in Solution

5.8 Reptation Model of Molecular Motion

5.9 Water-Soluble Polymers

5.10 Uses of High-Viscosity Polymer Solutions

5.11 Polymer Melts

Methods of Determining Relative Molar Mass

6.1 Introduction

6.2 Molar Masses from Colligative Properties

6.3 Light Scattering

6.4 Viscosity Methods of Determining Relative Molar Mass

6.5 End Group Analysis

6.6 Gel Permeation Chromatography

Mechanical Properties of Polymers

7.1 Introduction

7.2 Stress, Strain, and Young's Modulus

7.3 Brittle and Tough Fracture

7.4 Types of Strength

7.5 The Influence of Surfaces

7.6 Viscoelasticity

7.7 Creep and Stress Relaxation

7.8 Cold Drawing

7.9 Dynamic Tests

7.10 Time/Temperature Relationship

7.11 Rubberlike Elasticity

7.12 Reinforced Polymers

7.13 Practical Measurements of Mechanical Properties

7.14 Further Reading

Polymer Degradation

8.1 Introduction

8.2 Behaviour of Polymers In Fires

8.3 Assessment of Combustion Behaviour

8.4 Improvement of Stability of Polymers in Fires

8.5 Weathering of Polymers

8.6 Protection of Polymers from Photo-oxidation

8.7 Biological Degradation of Polymers

8.8 Exploitation of Polymer Degradation

Dendrimers

9.1 Introduction

9.2 Organic Dendrimers

9.3 Supramolecular Dendrimers

9.4 Shapes and Conformations of Dendrimers

9.5 Dendrimer Micelles

9.6 Characterization of Dendrimers

9.7 Applications of Dendrimers

9.8 Megamers

Special Topics in Polymer Chemistry

10.1 Introduction

10.2 Polymers in Medicine

10.3 Ionomers

10.4 Electronically Conducting Polymers

10.5 Interpenetrating Polymer Networks

10.6 Inorganic Polymers

10.7 Polymer Liquid Crystals

10.8 Polymers for Food Packaging

Polymers and the Environment

11.1 Introduction

11.2 Pollution by Polymers

11.3 The Nature of the Problem

11.4 Polymers and Energy

11.5 Recycling of Polymers

11.6 Degradable Polymers

11.7 The Future