书籍目录
书籍简介
本书pdf是文字版的。基本上就是传统物理化学中的化学热力学部分的那些内容的讨论。
Introduction
1.1 Basic concepts
1.2 Brief review of thermodynamics 【热力学第一第二定律】
1.3 The fundamental equation of thermodynamics 【equation】
1.4 The calculus of thermodynamics 【热力学公式的微积分处理】
1.5 Open systems
1.6 Legendre transforms and free energies 【自由能】
Single component systems
2.1 General phase behavior
2.2 Conditions for phase equilibrium 【相变的平衡】
2.3 The Clapeyron equation
Multicomponent systems
3.1 Thermodynamics of multicomponent systems
3.2 Binary mixtures
3.3 Ternary mixutures
The ideal solution model
4.1 Definition of the ideal solution model
4.2 Derivation of Raoult's law
Partial molar properties
5.1 Definition
5.2 Relationship between total properties and partial molar properties
5.3 Properties changes on mixing
5.4 Graphical representation for binary systems
Noideal solutions
6.1 Deviations from Raoult's law and the activity coefficient
6.2 Modified Raoult's law
6.3 Empirical activity coefficient models
6.4 The Gibbs-Duhem equation
6.5 Azeotropic systems
Stability
7.1 Introduction
7.2 Liquid-liquid equilibrium
Solid-liquid equilibrium
8.1 Introduction
8.2 Phase behavior
8.3 Conditions for equilibrium
Gas solubility and Henry's law
9.1 Henry's law
9.2 Activity coefficients
Equations of state
10.1 The principle of corresponding states
10.2 The van der Waals equation and cubic equations of state
10.3 Equations of state for mixtures
Thermodynamics from equations of state
11.1 The residual Helmholtz free energy
11.2 Fugacity 【逸度】
11.3 Vapor-liquid equilibrium with a non-ideal vapor phase
Chemical reaction equilibria
12.1 Conditions for equilibrium
12.2 The phase rule for chemically reacting systems
12.3 Gas phase reactions
12.4 The standard Gibbs free energy of formation
12.5 The influence of temperature
12.6 Liquid phase reactions